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This issue regroups topics that are related to the effects of the molecular structure in heterogeneous electron transfer kinetics. Subjects related to the interfacial structure include the distribution of charge in the double layer, the effects of specifically absorbed ions and molecules, and self- assembled monolayers. As for the reactant and the product of reaction, the topics cover effects of charge distribution within polyatomic reactants, and the position and orientation of the reactant at the interface (at metal or biological interfaces).

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