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The papers included in this issue of ECS Transactions were originally presented in the symposium “Electron Transfer and Energy Applications of Fullerenes and Nanostructured Materials, Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes, Carbon Nanotubes and Nanostructures: Applications and Devices, Carbon Nanotubes and Nanostrucutes: Medince and Biology, Porphyrins and Supramolecular Assemblies, Nanostructures for Energy Conversion, and Chemistry and Physics of Graphene and 2D Nanostructures”, held during the 221st meeting of The Electrochemical Society, in Seattle, Washington, from May 6 to 10, 2012.